We cannot tell electrons apart. All electrons have the
same mass, the same charge. All electrons in the ground state in the
atom of which they are a part all have the same energy, if the atom
is the same element. In the same sense, we cannot tell atoms apart.
If two atoms are the same element, with the same number of neutrons,
both in the ground state, we cannot say which is which.
If an element is radioactive, made up of atoms, all in
the same state, then we cannot say at any point which atom will decay
in the next time period. All atoms will decay with equal probability.
Radioactive decay is a truly random process, not affected by any
external conditions – pressure, temperature etc. Although the
process of decay is a random process, we can make useful predictions.
If we start with a large number of atomswe
can expect a certain number to decay in the next time period. Ifwere
larger we would expect more decays. On average the rate of decay is
proportional to the number of atoms in the sample. We can write
whereis
a constant, called the decay constant. The – sign indicates thatis
decreasing.
By writingwe
can see can see that in a time(whereis
infinitesimally small) a fractionof
theatoms
present will decay on average. This is a prediction. If we have lots
of samples, all withatoms
initially, sometimes slightly more atoms will decays, sometimes
slightly less.
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